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Sorry Resultz, There doesn't appear to be a way
Sorry, there's no way to get Fake Out on Aipom without the National Pokedex or trading. Once you get the Nat'l Dex though, it's pretty easy.
Meowth (Fake Out [Level - 9]) -> Aipom
Glameow (Fake Out [Auto]) -> Aipom
Skitty (Fake Out [Auto]) ->...
From EV Training Guide on Pokemon Platinum Board on GameFAQs
An EV, or effort value (sometimes referred to as effort points or EPs) is a point naturally gained by pokemon when they gain experience. So this means through the EXP Share as well as normal fighting. This point can be in any of the...