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if you open the meta data is the file named without the png extension? like trchar000?
and do you have each outfit named trchar000_1, trchar000_2, etc?
It depends on what you want to do, and how you want it done.
In my game they are items in a certain bag slot, but in x/y, it is done in the back of the pokemon center.
All you really need to do to accomplish the task set in x/y is:
Spoiler:
You should also look up a thread about outfits, it was a while back, but someone had trouble setting it up, and in it, is explained everything you'd need to work it.
There are some limitations as of essentials 13, but what you want should work fine.