I quite like Heat Rotom. With only Rock and Water as weaknesses, eight resistances, and a Ground immunity, it has an excellent defensive typing, and it gets access to Volt Switch to get a hit in whenever it has to switch out from Overheat's special attack debuff.
I like all of the other forms too, except Wash Rotom. (I don't like using low-accuracy moves if I can help it, and Hydro Pump only has 80 accuracy. At least Blizzard hits consistently on hail teams, which I probably have already if I'm using Frost Rotom in the first place.)