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You guys need to start ad-libing names as I do xD That makes the post longer xDDD
Still... this was a bad idea... now there are posts replying to pics that aren't even there...
Switching bodies, KyoAni-like animation, that's nothing less than Kokoro Scandal Connect.
Your right it was Black Cat as for your pic one of the most well known imouto characters today.
Kirino from Ore no Imouto ga Konnani Kawaii Wake ga Nai.